CoMoO4 nanobelts as efficient peroxidase mimics for the colorimetric determination of H2O2

doi:10.1007/s00604-020-04376-7

	CoMoO4 nanobelts as efficient peroxidase mimics for the colorimetric determination of H2O2
	Wang, Zhe 1,2; Ju, Peng2,3,4 ; Zhang, Yu2 ; Jiang, Fenghua 2; Ding, Haibing 1; Sun, Chengjun 2,5
	2020-07-03
发表期刊	MICROCHIMICA ACTA
ISSN	0026-3672
卷号	187 期号:8 页码:14
通讯作者	Ding, Haibing(dinghb@ouc.edu.cn) ; Sun, Chengjun(csun@fio.org.cn)
摘要	CoMoO4 materials were prepared through a simple hydrothermal method and developed as highly efficient peroxidase mimics for colorimetric determination of H2O2. Based on the different experimental conditions in the synthesis process, the CoMoO4 materials present distinct morphologies, structures, surface properties, and peroxidase mimetic activities. Among them, CoMoO4 nanobelts (NBs) display the best intrinsic peroxidase mimetic abilities due to the high-energy (100) facet exposed, more Co active sites at (100) facet, more negative potential, and larger specific surface area. It can efficiently catalyze the oxidation of 3,3,5,5-tetramethylbenzidine (TMB) in the presence of H2O2 to generate a blue oxide. In view of the excellent peroxidase mimetic catalytic activity of CoMoO4 NBs, a rapid, convenient, and ultrasensitive method was successfully established for the visual and colorimetric determination of H2O2. The method exhibits good selectivity, practicability, stability, and reusability, and has a detection limit of 0.27 mu M. The peroxidase mimetic catalytic mechanism of CoMoO4 NBs was illustrated according to the kinetic and active species trapping experiments. The method has a good potential for rapid and sensitive determination of H2O2 for biomedical analysis. Schematic presentation of the process of CoMoO4 nanobelts catalyzing the oxidation of peroxidase substrate 3,3 ' ,5,5 ' -tetramethylbenzidine (TMB) in the presence of H2O2 to generate a typical blue color, which can be applied in rapid and ultrasensitive detection of H2O2 visually.
关键词	Peroxidase mimics Catalytic mechanism Rapid detection Selectivity Kinetics Nanobelts XRD SEM TMB H2O2
DOI	10.1007/s00604-020-04376-7
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51702328] ; Shandong Provincial Natural Science Foundation[ZR2017BD002] ; Basic Scientific Fund for National Public Research Institutes of China[2019Y03] ; Basic Scientific Fund for National Public Research Institutes of China[2020S02] ; CAS Light of West China Program ; Open Fund of Laboratory for Marine Ecology and Environmental Science ; Pilot National Laboratory for Marine Science and Technology (Qingdao)[LMEES201802] ; Open Fund of Shandong Key Laboratory of Corrosion Science[KLCS201906] ; China Postdoctoral Science Foundation[2017M622179] ; China Postdoctoral Science Foundation[2018T110681] ; Open Foundation of Pilot National Laboratory for Marine Science and Technology (Qingdao)[QNLM2016ORP0410] ; The Aoshan Scientific and Technological Innovation Project - Pilot National Laboratory for Marine Science and Technology (Qingdao)[2016ASKJ14] ; Ministry of Human Resources and Social Security of China
WOS研究方向	Chemistry
WOS类目	Chemistry, Analytical
WOS记录号	WOS:000550628700002
出版者	SPRINGER WIEN
引用统计	被引频次：22[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/167985
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Ding, Haibing; Sun, Chengjun
作者单位	1.Ocean Univ China, Key Lab Marine Chem Theory & Technol, Minist Educ, 238 Songling Rd, Qingdao 266100, Peoples R China 2.Minist Nat Resources MNR, Key Lab Marine Bioact Subst & Analyt Technol, Marine Biol Resources & Environm Res Ctr, Inst Oceanog 1, 6 Xianxialing Rd, Qingdao 266061, Peoples R China 3.Pilot Natl Lab Marine Sci & Technol Qingdao, Lab Marine Ecol & Environm Sci, 1 Wenhai Rd, Qingdao 266237, Peoples R China 4.Chinese Acad Sci, Inst Oceanol, Shandong Key Lab Corros Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China 5.Pilot Natl Lab Marine Sci & Technol Qingdao, Lab Marine Drugs & Bioprod, 1 Wenhai Rd, Qingdao 266237, Peoples R China
推荐引用方式 GB/T 7714	Wang, Zhe,Ju, Peng,Zhang, Yu,et al. CoMoO4 nanobelts as efficient peroxidase mimics for the colorimetric determination of H2O2[J]. MICROCHIMICA ACTA,2020,187(8):14.
APA	Wang, Zhe,Ju, Peng,Zhang, Yu,Jiang, Fenghua,Ding, Haibing,&Sun, Chengjun.(2020).CoMoO4 nanobelts as efficient peroxidase mimics for the colorimetric determination of H2O2.MICROCHIMICA ACTA,187(8),14.
MLA	Wang, Zhe,et al."CoMoO4 nanobelts as efficient peroxidase mimics for the colorimetric determination of H2O2".MICROCHIMICA ACTA 187.8(2020):14.

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