Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction

doi:10.1002/advs.202100076

	Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction
	Wang, Nan1,2,3 ; Ma, Shaobo 4; Zuo, Pengjian 4; Duan, Jizhou 1,2,3; Hou, Baorong 1,2,3
	2021-05-27
发表期刊	ADVANCED SCIENCE
页码	26
通讯作者	Ma, Shaobo(shaobomahit@gmail.com) ; Zuo, Pengjian(zuopj@hit.edu.cn) ; Duan, Jizhou(duanjz@qdio.ac.cn)
摘要	Shifting electrochemical oxygen reduction reaction (ORR) via two-electron pathway becomes increasingly crucial as an alternative/green method for hydrogen peroxide (H2O2) generation. Here, the development of 2e(-) ORR catalysts in recent years is reviewed, in aspects of reaction mechanism exploration, types of high-performance catalysts, factors to influence catalytic performance, and potential applications of 2e(-) ORR. Based on the previous theoretical and experimental studies, the underlying 2e(-) ORR catalytic mechanism is firstly unveiled, in aspect of reaction pathway, thermodynamic free energy diagram, limiting potential, and volcano plots. Then, various types of efficient catalysts for producing H2O2 via 2e(-) ORR pathway are summarized. Additionally, the catalytic active sites and factors to influence catalysts' performance, such as electronic structure, carbon defect, functional groups (O, N, B, S, F etc.), synergistic effect, and others (pH, pore structure, steric hindrance effect, etc.) are discussed. The H2O2 electrogeneration via 2e(-) ORR also has various potential applications in wastewater treatment, disinfection, organics degradation, and energy storage. Finally, potential future directions and prospects in 2e(-) ORR catalysts for electrochemically producing H2O2 are examined. These insights may help develop highly active/selective 2e(-) ORR catalysts and shape the potential application of this electrochemical H2O2 producing method.
关键词	application catalytic mechanism electrochemical catalysts hydrogen peroxide two‐ electron oxygen reduction reaction
DOI	10.1002/advs.202100076
收录类别	SCI
语种	英语
资助项目	Key Research Program of Frontier Sciences, Chinese Academy of Sciences[ZDBS-LY-DQC025] ; National Natural Science Foundation of China[41827805] ; Shandong Key Laboratory of Corrosion Science ; University of Chinese Academy of Sciences (UCAS)
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000655406800001
出版者	WILEY
引用统计	被引频次：207[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/171011
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Ma, Shaobo; Zuo, Pengjian; Duan, Jizhou
作者单位	1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Ctr Ocean Megasci, 7 Nanhai Rd, Qingdao 266071, Peoples R China 3.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China 4.Harbin Inst Technol, Sch Chem & Chem Engn, MITT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China
第一作者单位	中国科学院海洋研究所; 中国科学院海洋大科学研究中心
通讯作者单位	中国科学院海洋研究所; 中国科学院海洋大科学研究中心
推荐引用方式 GB/T 7714	Wang, Nan,Ma, Shaobo,Zuo, Pengjian,et al. Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction[J]. ADVANCED SCIENCE,2021:26.
APA	Wang, Nan,Ma, Shaobo,Zuo, Pengjian,Duan, Jizhou,&Hou, Baorong.(2021).Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction.ADVANCED SCIENCE,26.
MLA	Wang, Nan,et al."Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction".ADVANCED SCIENCE (2021):26.

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