Co-sensitization of TiO2 nanotube arrays with polymerized aromatic amines and its application in photoelectrochemical cathodic protection

doi:10.1016/j.jelechem.2021.115749

	Co-sensitization of TiO2 nanotube arrays with polymerized aromatic amines and its application in photoelectrochemical cathodic protection
	Wang, Chunli 1,2,3; Liu, Nazhen 2,3; Wang, Ning 2,3; Ma, Zheng 2,3; Tian, Yong 4; Wang, Lifei 2,3; Chen, Xuwei 1; Hou, Baorong 2,3
	2021-11-15
发表期刊	JOURNAL OF ELECTROANALYTICAL CHEMISTRY
ISSN	1572-6657
卷号	901 页码:9
通讯作者	Liu, Nazhen(liunazhen@qdio.ac.cn) ; Chen, Xuwei(chenxuwei@mail.neu.edu.cn)
摘要	In this work, an initiator-free polymerization of 4,4'-diaminobiphenyl (DABP) happened on the TiO2 nanotube arrays (TNT/Ti) via a facile in-situ solvothermal synthesis method. The poly-4,4'-diaminobiphenyl (PDABP) modified TNT/Ti (PDABP/TNT/Ti) composite was fully characterized by SEM, XRD, FTIR, and XPS. The prepared PDABP/TNT/Ti exhibited stronger visible light absorption, improved separation of photogenerated charge carriers, reduced charge transfer resistance at the interface, and enhanced reducing capability of photoelectrons (as indicated by the more negative energy level of the conduction band, ECB). Attributed to the formation of the type II heterostructure between TiO2 and PDABP, the PDABP/TNT/Ti showed enhanced photoelectrochemical (PEC) cathodic performance by polarizing the potential of 304 stainless steel (304SS) to similar to-900 mV in a 3.5 wt% NaCl. By replacing monomers, the strategy of enhancing the PEC cathodic protection performance of TNT/Ti using electrically conducting polymers of aromatic amines was confirmed to be simple and effective.
关键词	Initiator-free Polymerized aromatic amines conducting polymer TiO2 nanotubes Photocathodic protection 304 stainless steel
DOI	10.1016/j.jelechem.2021.115749
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Electrochemistry
WOS类目	Chemistry, Analytical ; Electrochemistry
WOS记录号	WOS:000709805200013
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/176759
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Liu, Nazhen; Chen, Xuwei
作者单位	1.Northeastern Univ, Coll Sci, Res Ctr Analyt Sci, Dept Chem, Box 332, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 3.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China 4.Qingdao Univ Technol, Sch Environm & Municipal Engn, 11 Fushun Rd, Qingdao 266033, Peoples R China
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Wang, Chunli,Liu, Nazhen,Wang, Ning,et al. Co-sensitization of TiO2 nanotube arrays with polymerized aromatic amines and its application in photoelectrochemical cathodic protection[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2021,901:9.
APA	Wang, Chunli.,Liu, Nazhen.,Wang, Ning.,Ma, Zheng.,Tian, Yong.,...&Hou, Baorong.(2021).Co-sensitization of TiO2 nanotube arrays with polymerized aromatic amines and its application in photoelectrochemical cathodic protection.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,901,9.
MLA	Wang, Chunli,et al."Co-sensitization of TiO2 nanotube arrays with polymerized aromatic amines and its application in photoelectrochemical cathodic protection".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 901(2021):9.

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