Effect of hydrogen treatment on the photoelectrochemical properties of quantum dots sensitized ZnO nanorod array
Bu, Yuyu; Chen, Zhuoyuan; Chen, ZY (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China.
2014-12-25
发表期刊JOURNAL OF POWER SOURCES
卷号272页码:647-653
文章类型Article
摘要The hydrogenated ZnO nanorod array (NRA) was, for the first time, applied to the field of quantum dots (QDs) sensitized photoanodes. Hydrogen treatment at high temperature can significantly change the surface states of ZnO NRA. Partial oxygen atoms on the surface of ZnO are taken away by hydrogen, resulting in the formation of oxygen vacancies. The formation of oxygen vacancies significantly enhances the charge carrier density and the electron migration ability of ZnO NRA. Meanwhile, the energy barrier of the injection of the photoinduced electrons generated by CdS into ZnO NRA decreases due to the formation of doping energy levels under the conducting band of ZnO. Therefore, the photoelectrochemical performance of CdS QDs sensitized hydrogenated ZnO NRA is significantly improved. This work has potential significance in enhancing the performance of QDs sensitized solar cell as well as dye sensitized solar cell. (C) 2014 Elsevier B.V. All rights reserved.
关键词Hydrogen Treatment Zno Nanorod Array Quantum Dots Photoelectrochemical Property Oxygen Vacancy
学科领域Electrochemistry ; Energy & Fuels
DOI10.1016/j.jpowsour.2014.08.127
收录类别SCI
语种英语
WOS记录号WOS:000344208700080
引用统计
被引频次:37[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/23868
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Chen, ZY (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China.
作者单位Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
第一作者单位中国科学院海洋研究所
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Bu, Yuyu,Chen, Zhuoyuan,Chen, ZY . Effect of hydrogen treatment on the photoelectrochemical properties of quantum dots sensitized ZnO nanorod array[J]. JOURNAL OF POWER SOURCES,2014,272:647-653.
APA Bu, Yuyu,Chen, Zhuoyuan,&Chen, ZY .(2014).Effect of hydrogen treatment on the photoelectrochemical properties of quantum dots sensitized ZnO nanorod array.JOURNAL OF POWER SOURCES,272,647-653.
MLA Bu, Yuyu,et al."Effect of hydrogen treatment on the photoelectrochemical properties of quantum dots sensitized ZnO nanorod array".JOURNAL OF POWER SOURCES 272(2014):647-653.
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