Institutional Repository of Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences
| Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii | |
Zhang, Peng1,2 ; Mandi, Attila3; Li, Xiao-Ming1; Du, Feng-Yu1; Wang, Jia-Ning1,2; Li, Xin1,2; Kurtan, Tibor3; Wang, Bin-Gui1; Kurtan, T (reprint author), Debrecen Univ Med, Dept Organ Chem, POB 20, H-4010 Debrecen, Hungary.
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| 2014-09-19 | |
| 发表期刊 | ORGANIC LETTERS
 |
| 卷号 | 16期号:18页码:4834-4837 |
| 文章类型 | Article |
| 摘要 | A new 3H-oxepine-containing alkaloid, varioxepine A (1), characterized by a structurally unprecedented condensed 3,6,8-trioxabicyclo[3.2.1]octane motif, was isolated from the marine algal-derived endophytic fungus Paecilomyces variotii. Due to the low proton/carbon ratio, the unambiguous assignment of the planar structure and relative configuration was precluded by NMR experiments and solved by single crystal X-ray analysis. The absolute configuration was established by DFT conformational analysis and TDDFT-ECD calculations. Compound 1 inhibited plant pathogenic fungus Fusarium graminearum. |
| 学科领域 | Chemistry |
| DOI | 10.1021/ol502329k |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000342117600036 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/24191 |
| 专题 | 实验海洋生物学重点实验室 |
| 通讯作者 | Kurtan, T (reprint author), Debrecen Univ Med, Dept Organ Chem, POB 20, H-4010 Debrecen, Hungary. |
| 作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Expt Marine Biol, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Debrecen Univ Med, Dept Organ Chem, H-4010 Debrecen, Hungary |
| 第一作者单位 | 实验海洋生物学重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang, Peng,Mandi, Attila,Li, Xiao-Ming,et al. Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii[J]. ORGANIC LETTERS,2014,16(18):4834-4837. |
| APA | Zhang, Peng.,Mandi, Attila.,Li, Xiao-Ming.,Du, Feng-Yu.,Wang, Jia-Ning.,...&Kurtan, T .(2014).Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii.ORGANIC LETTERS,16(18),4834-4837. |
| MLA | Zhang, Peng,et al."Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii".ORGANIC LETTERS 16.18(2014):4834-4837. |
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Varioxepine A, a 3H-（949KB） | 限制开放 | ODC PDDL | 浏览 | |||
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