Evaluation of the pyrolytic and kinetic characteristics of Enteromorpha prolifera as a source of renewable bio-fuel from the Yellow Sea of China

doi:10.1016/j.cherd.2009.10.011

IOCAS-IR > 实验海洋生物学重点实验室

	Evaluation of the pyrolytic and kinetic characteristics of Enteromorpha prolifera as a source of renewable bio-fuel from the Yellow Sea of China
	Li, Demao 2; Chen, Limei 2; Zhao, Jinsheng 3; Zhang, Xiaowen 1; Wang, Qingyin 1; Wang, Hongxia 4; Ye, Naihao 1
	2010-05-01
发表期刊	CHEMICAL ENGINEERING RESEARCH & DESIGN
ISSN	0263-8762
卷号	88 期号:5-6A 页码:647-652
文章类型	Article
摘要	The pyrolytic and kinetic characteristics of Enteromorpha prolifera from the Yellow Sea were evaluated at heating rates of 10, 20 and 50 degrees C min(-1), respectively. The results indicated that three stages appeared during pyrolysis; dehydration, primary devolatilization and residual decomposition. Differences in the heating rates resulted in considerable differences in the pyrolysis of E. prolifera. Specifically, the increase of heating rates resulted in shifting of the initial temperature, peak temperature and the maximum weight loss to a higher value. The average activation energy of E. prolifera was 228.1 kJ mol(-1), the pre-exponential factors ranged from 49.93 to 63.29 and the reaction orders ranged from 2.2 to 3.7. In addition, there were kinetic compensation effects between the pre-exponential factors and the activation energy. Finally, the minimum activation energy was obtained when a heating rate of 20 degrees C min(-1) was used. (C) 2009 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.; The pyrolytic and kinetic characteristics of Enteromorpha prolifera from the Yellow Sea were evaluated at heating rates of 10, 20 and 50 degrees C min(-1), respectively. The results indicated that three stages appeared during pyrolysis; dehydration, primary devolatilization and residual decomposition. Differences in the heating rates resulted in considerable differences in the pyrolysis of E. prolifera. Specifically, the increase of heating rates resulted in shifting of the initial temperature, peak temperature and the maximum weight loss to a higher value. The average activation energy of E. prolifera was 228.1 kJ mol(-1), the pre-exponential factors ranged from 49.93 to 63.29 and the reaction orders ranged from 2.2 to 3.7. In addition, there were kinetic compensation effects between the pre-exponential factors and the activation energy. Finally, the minimum activation energy was obtained when a heating rate of 20 degrees C min(-1) was used. (C) 2009 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
关键词	Enteromorpha Prolifera Pyrolysis Kinetics
学科领域	Engineering, Chemical
DOI	10.1016/j.cherd.2009.10.011
URL	查看原文
收录类别	SCI
语种	英语
WOS记录号	WOS:000279361900014
引用统计	被引频次：87[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/5864
专题	实验海洋生物学重点实验室
作者单位	1.Yellow Sea Fisheries Res Inst, Key Lab Sustainable Utilizat Marine Fishery Resou, Qingdao 266071, Peoples R China 2.Liaocheng Univ, Dept Food Sci, Coll Agr, Liaocheng 252059, Peoples R China 3.Liaocheng Univ, Chem & Chem Engn Coll, Liaocheng 252059, Peoples R China 4.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
推荐引用方式 GB/T 7714	Li, Demao,Chen, Limei,Zhao, Jinsheng,et al. Evaluation of the pyrolytic and kinetic characteristics of Enteromorpha prolifera as a source of renewable bio-fuel from the Yellow Sea of China[J]. CHEMICAL ENGINEERING RESEARCH & DESIGN,2010,88(5-6A):647-652.
APA	Li, Demao.,Chen, Limei.,Zhao, Jinsheng.,Zhang, Xiaowen.,Wang, Qingyin.,...&Ye, Naihao.(2010).Evaluation of the pyrolytic and kinetic characteristics of Enteromorpha prolifera as a source of renewable bio-fuel from the Yellow Sea of China.CHEMICAL ENGINEERING RESEARCH & DESIGN,88(5-6A),647-652.
MLA	Li, Demao,et al."Evaluation of the pyrolytic and kinetic characteristics of Enteromorpha prolifera as a source of renewable bio-fuel from the Yellow Sea of China".CHEMICAL ENGINEERING RESEARCH & DESIGN 88.5-6A(2010):647-652.

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